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专项名称 : 政府间国际科技创新合作重点专项
项目名称 : 面向高湿热海洋环境服役的新型防腐防污非晶涂层的研制
项目编号 : 2021YFE0100600
说明 :

海洋蕴藏着丰富的资源,探索与开发海洋资源具有重要的经济价值和战略意义。近年来,中国与巴基斯坦都高度重视海洋资源的开发,并于 2015 年签订共建“中巴联合海洋研究中心”的议定书,以推进双方在材料科技与海洋工程领域的务实合作。经略海洋,装备先行。中国南海和巴基斯坦阿拉伯海域的海洋环境十分相似(高热、 高湿、高盐),海洋工程装备及构件服役面临严重的腐蚀与污损问题,造成了巨大的经济损失。如何提高中巴两国海洋装备及用材的使用性能、延长其服役寿命,是两国海洋工业亟待解决的重大共性问题,而开发新型高性能防腐防污功能一体化金属涂层技术是双方共同关注的研究热点。

本项目拟解决的关键科学问题是: 1)非晶涂层在高湿高热海洋环境下的点蚀机理; 2)非晶涂层防污元素的可控注入与释放及防污机理; 3)纹理化结构的非晶复合涂层的防腐防污机理。拟采取的技术路线为:防污耐蚀非晶涂层的成分设计、非晶涂层防污元素的可控注入与可控释放、纹理化超疏水非晶涂层制备与表征、非晶涂层的结构表征/调控及服役性能测试、非晶涂层的点蚀机理分析、非晶涂层的防污性能表征与污损机理分析。

为了解决上述科学问题,本合作项目提出共同研发出面向高湿热海洋环境应用的1-2 种新型防腐防污功能一体化非晶涂层材料技术,深入分析微生物等因素对非晶涂层腐蚀和污损行为的影响,揭示点其蚀机制;阐明化学成分、纳米晶化及表面结构对非晶涂层腐蚀、污损性能的影响规律;评估所研发的新型 Fe 基非晶涂层在两国海洋工程领域应用的可行性。合作研究内容包括:(1)防腐防污功能一体化的非晶涂层的成分设计与制备;(2)防腐防污非晶涂层的结构表征与调控;(3)非晶涂层的力学性能、腐蚀性能及微生物污损性能的研究;(4)纹理化结构的非晶复合涂层的设计与腐蚀污损性能研究。

本项目中方团队为华中科技大学非晶态材料研究室,是国内最早从事非晶涂层技术研究的研究组之一,在非晶涂层体系设计及涂层制备技术方面具有深厚的工作积累。合作方为巴基斯坦伊斯兰堡空间技术研究所的热喷涂实验室(团队 PI 为 Yasir 博士,于 2016 年博士毕业于中方研究组),该团队一直从事热喷涂涂层技术研究,获巴基斯坦高等教育委员会基金项目、中国-巴基斯坦国家自然科学基金合作项目等多项涂层相关项目资助,在涂层制备技术、腐蚀测试与机理分析等方面具有优势。

本项目预期在新理论方面的成果包括 :防腐防污非晶涂层的成分设计理论;超疏水-防污剂协同提升非晶涂层防腐防污性能作用机制。预期在新方法方面的成果包括:纹理化非晶涂层制备关键技术;低表面能非晶涂层制备关键技术;超疏水-防污剂协同作用表面涂层技术。预期在成果数量指标包括:发表国际期刊论文 10篇;申报国家发明专利 4 项。本项目研发的高耐久性防腐防污一体化涂层技术有望大幅降低因海洋腐蚀或污损引起的经济损失;同时将加强两国学者之间的交流,提升我国防腐防污涂层材料研究在国际上的影响力,促进中巴两国间先进材料技术创新合作与技术转移,服务中国-巴基斯坦政府间的科技外交,推进我国“一带一路”的建设。

根据本项目的特点,研发过程的主要数据产生源头为非晶涂层的微生物腐蚀机制研究、防腐防污功能一体化的非晶涂层的成分设计与制备技术、防腐防污非晶涂层的结构表征与性能调控、纹理化结构的非晶复合涂层的设计与腐蚀污损性能研究。

英文说明 :

The ocean is rich in resources, exploring and developing the ocean resources has important economic value and strategic significance. In recent years, China and Pakistan have attached great importance to the development of Marine resources, and in 2015 signed a protocol to jointly build a "China-Pakistan Joint Marine research Center" to promote practical cooperation between the two sides in the field of materials science and technology and ocean engineering. The sea, equipment first. The Marine environment of the South China Sea and the Pakistan-Arabian Sea is very similar (high heat, high humidity, high salt), and the Marine engineering equipment and components are facing serious corrosion and fouling problems in service, causing huge economic losses. How to improve the service performance and extend the service life of Marine equipment and materials in China and Brazil is a major common problem to be solved urgently in the Marine industry of the two countries, and the development of new high-performance integrated metal coating technology with anti-corrosion and anti-pollution functions is a research hotspot of both sides.

The key scientific problems to be solved in this project are: 1) pitting mechanism of amorphous coatings in high humidity and high heat ocean environment; 2) Controlled injection and release of anti-fouling elements and anti-fouling mechanism of amorphous coating; 3) Anti-fouling mechanism of textured amorphous composite coating. The proposed technical route is as follows: composition design of antifouling and corrosion resistant amorphous coating, controlled injection and controlled release of antifouling elements of amorphous coating, preparation and characterization of textured superhydrophobic amorphous coating, structural characterization/regulation and service performance test of amorphous coating, pitting mechanism analysis of amorphous coating, antifouling performance characterization and fouling mechanism analysis of amorphous coating.

In order to solve the above scientific problems, the cooperation project proposed to jointly develop 1-2 new anti-corrosion and anti-fouling function integrated amorphous coating material technology for applications in high humid and hot Marine environment, in-depth analysis of microbial and other factors on the corrosion and fouling behavior of amorphous coating, and reveal its corrosion mechanism; The effects of chemical composition, nanocrystallization and surface structure on corrosion and fouling properties of amorphous coatings are described. To evaluate the feasibility of the new Fe-based amorphous coating developed in the field of Marine engineering in the two countries. The cooperative research includes: (1) composition design and preparation of amorphous coatings with integrated anti-corrosion and anti-fouling functions; (2) Structural characterization and control of anti-corrosion and anti-fouling amorphous coatings; (3) Research on mechanical properties, corrosion properties and microbial fouling properties of amorphous coatings; (4) Design of textured amorphous composite coatings and study on corrosion damage performance.

The Chinese team in this project is the Amorphous Materials Laboratory of Huazhong University of Science and Technology, which is one of the earliest research groups engaged in the research of amorphous coating technology in China, and has profound work accumulation in the design of amorphous coating system and coating preparation technology. The partner is the Thermal Spraying Laboratory of the Institute of Space Technology, Islamabad, Pakistan (team PI is Dr. Yasir, who graduated from the Chinese research team in 2016), and the team has been engaged in the research of thermal spraying coating technology. Funded by Pakistan Higher Education Commission Fund project, China-Pakistan National Natural Science Foundation cooperation project and many other coating related projects, it has advantages in coating preparation technology, corrosion testing and mechanism analysis.

The expected new theoretical results of this project include: composition design theory of anti-fouling and antifouling amorphous coatings; The mechanism by which superhydrophobic and antifouling agents cooperate to improve the anti-fouling performance of amorphous coatings. The expected achievements in new methods include: key techniques for the preparation of textured amorphous coatings; Key technology of low surface energy amorphous coating; Superhydrophobic - antifouling agent synergistic surface coating technology. The expected number of results included: 10 articles published in international journals; 4 national invention patents were declared. The integrated coating technology of high durability anticorrosion and antifouling developed by this project is expected to significantly reduce economic losses caused by Marine corrosion or fouling; At the same time, it will strengthen the exchanges between scholars of the two countries, enhance the international influence of China's anti-corrosion and antifouling coating materials research, promote the technological innovation cooperation and technology transfer of advanced materials between China and Pakistan, serve the science and technology diplomacy between the Chinese and Pakistani governments, and promote the construction of China's "Belt and Road".

According to the characteristics of the project, the main data generation sources of the research and development process are the study of the microbial corrosion mechanism of the amorphous coating, the composition design and preparation technology of the amorphous coating with integrated anti-corrosion and anti-fouling functions, the structural characterization and performance control of the amorphous coating with anti-fouling and anti-fouling structure, the design of the amorphous composite coating with textured structure and the study of corrosion and fouling performance.

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