本发明提供了一种制备3D打印用稀土氧化物掺杂钨、钼球形粉末的方法,属于粉末冶金粉末制备技术领域。具体制备方法为:采用低温溶液燃烧合成法制备稀土氧化物/氧化钨(氧化钼)复合粉末,然后通过氢气还原得到稀土氧化物掺杂的纳米钨(钼)粉末,接着使用喷雾造粒设备将纳米粉末进行造粒,造粒粉末经过煅烧、研磨、筛分后得到可用于3D打印的球形钨(钼)粉末。本发明原料简单易得,设备简单,工艺快捷,可以在短时间内制备大量的产物,适合大规模生产。制备的钨、钼球形粉末中稀土氧化物可以均匀地分散,且颗粒细小,不会出现氧化物粒子的偏聚,且稀土氧化物的加入量可以通过低温溶液燃烧合成过程进行调整。所制备的钨、钼球形粉末的球形度和流动性优异,极为适合3D打印工艺。
The invention provides a method for preparing rare earth oxide doped tungsten and molybdenum spherical powders for 3D printing, and belongs to the technical field of powder metallurgy powder preparation. The specific preparation method is as follows: the rare earth oxide/tungsten oxide (molybdenum oxide) composite powder is prepared by the low-temperature solution combustion synthesis method, and then the rare earth oxide-doped nano-tungsten (molybdenum) powder is obtained by hydrogen reduction, and then spray granulation equipment is used to The nano powder is granulated, and the granulated powder is calcined, ground, and sieved to obtain spherical tungsten (molybdenum) powder that can be used for 3D printing. The raw materials of the invention are simple and easy to obtain, the equipment is simple, and the process is fast, can prepare a large amount of products in a short time, and is suitable for large-scale production. The rare earth oxides in the prepared tungsten and molybdenum spherical powders can be uniformly dispersed, and the particles are fine, no segregation of oxide particles occurs, and the addition amount of the rare earth oxides can be adjusted through a low-temperature solution combustion synthesis process. The prepared tungsten and molybdenum spherical powders have excellent sphericity and fluidity, and are extremely suitable for 3D printing processes.