本发明公开了一种结构优化的手性超分子水凝胶基元的设计思路与制备方法，所述手性超分子水凝胶以苝酰亚胺、联苯、萘环等含大π键共轭结构疏水基团为中心核，在所述中心核两侧对称对称连接手性氨基酸基元。本发明通过优化中心核疏水基元，使其在分子自组装时，由于分子中心更大的π键共轭结构、使得分子间π‑π相互作用大大增强，协同手性氨基酸酰胺键间氢键作用，可获得手性组装结构更稳定的超分子水凝胶材料。

The invention discloses a design concept and preparation method for a structurally optimized chiral supramolecular hydrogel monomer. The chiral supramolecular hydrogel is centered around a hydrophobic core group containing a large π-bond conjugated structure, such as perylene imide, biphenyl, or naphthalene rings, with chiral amino acid units symmetrically connected on both sides of the core. By optimizing the hydrophobic core unit, the invention enhances the π-π interactions between molecules due to the larger π-bond conjugated structure at the molecular center, and synergizes with the hydrogen bonding between the amide bonds of the chiral amino acids, resulting in the formation of a more stable chiral assembly structure supramolecular hydrogel material.