在存在 BSA 的情况下,与 r-SBF 的数据相比,icorr 和 Rp 显示出几乎完全相反的趋势。 一般情况下,BSA首先加速纯Zn的腐蚀速度,然后将腐蚀抑制到14 d,除0.5和7 d外,应考虑计算方法的差异。 此外,从极化曲线可以观察到,在 r-SBF 中浸泡的前 6 小时,纯 Zn 仅显示小的钝化区。 然而,在这项工作中存在 BSA 的情况下,0 天和 0.5 天的样品会出现明显的钝化区域。 这种差异意味着 BSA 的快速吸附改变了纯 Zn 在浸泡初期的腐蚀行为。
In the presence of BSA the icorr and Rp show almost completely opposite trends compared with the data for r-SBF. Generally, BSA accelerates the corrosion rate of pure Zn at first and then suppress the corrosion till 14 d except for 0.5 and 7 d.The discrepancy of calculation methods should be taken into consideration. Additionally, from the polarization curves one can observed that in the first 6 h immersion in r-SBF, pure Zn only displays small passivation-like regions. However, in the presence of BSA in this work distinct passivation areas show up for 0 d and 0.5 d samples. This difference implicates that the rapid adsorption of BSA alters the corrosion behavior of pure Zn in the initial of immersion.