改性前后Ti3C2的羟基峰分别位于3430和3411 cm-1,1641,1627和 553 cm-1处的特征峰对应了未改性Ti3C2的稳定骨架结构。在GPS改性后,环氧集团在1238 cm-1出现了新的特征峰,印证了改性的成功进行。
To prove the epoxy functionalization of Ti3C2, FT-IR spectrum was recorded for U-Ti3C2 and E-Ti3C2 samples. As shown in the Figure, the OH groups could be revealed from the broad peaks at around 3430 and 3411 cm-1 for U-Ti3C2 and E-Ti3C2, respectively. The peaks at around 1641, 1627 and 553 cm-1 demonstrated the stable skeleton structure of U-Ti3C2 . After modification of Ti3C2 with GPS, a new peak at 1238 cm-1, attributing to the stretching vibration of epoxide group, appeared. The above results confirmed that GPS successfully modified Ti3C2.